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At NCpedia, we have to comply with copyright law in our use of images so I'm unable to provide you with any images from our collections at the Government & Heritage Library.
However, you may want to visit the Library of Congress website. The Library of Congress has thousands of images. And depending on how you're planning to use the image, many of them do not have copyright use restrictions. Users of the website's content are responsible for assessing whether or not their use of an image is allowable under copyright law.
Click on this link for search results for images of the Biltmore at the Library of Congress.
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Kelly Agan, NCpedia Staff